Publications in Scientific Journals:
F. Sauter, U. Jordis, G. Cai:
"Dehydrogenation of 2-ethylbenzenethiols: improved synthesis of benzo[b]thiophenes";
Journal of Chemical Research, Synopses,
The known procedure (Hansch, C.; et al., 1956) for the prepn. of benzo[b]thiophenes I (R = H, NH2) by catalytic dehydrogenation of 4,3-Et(HS)C6H3R (R as before) is improved by the use of readily accessible catalysts. These were Cu-Cr on activated charcoal or BASF catalysts V-1283 and H 3-10. The dehydrogenation app. (H.; 1953) is simplified by use of an infusion pump. I (R = H, NH2) were obtained in £73% and £65.2% yield, resp.
Created from the Publication Database of the Vienna University of Technology.