Publications in Scientific Journals:
U. Jordis, K. Bhattacharya, P. Boamah, V. Lee:
"Synthesis of thieno[2,3-d]-1,3-dithiol-2-thiones from thieno[2,3-d]-1,2,3-thiadiazoles: Matryoshka-type autoclave for high-temperature, high-pressure thermolysis microscale reactions";
Thieno[2,3-d]-1,2,3-thiadiazoles (1) react with carbon disulfide in a "Matryoshka-type" double compartment autoclave  to yield thieno[2,3-d]-1,3-dithiol-2-thiones (2). With BH3/Me2S the cyclic trithiocarbonate (2d) is cleaved and the product characterized after methylation as 4b. Compds. 7a and 7b are prepd. via the thieno[2,3-d]-1,3-dithiolium salts (6) followed by NaBH4-redn.
Created from the Publication Database of the Vienna University of Technology.